Numerical Study to Define Initial Thermal Integration Window for Methane Oxidative Coupling with Dehydroaromatization Reactors

نویسندگان

چکیده

Oxidative coupling of methane and dehydroaromatization are attractive one-step conversion routes to make valuable platform chemicals more sustainable. Both processes require elevated temperatures above 600°C, good heat management, the use heterogeneous catalysts. None these reactions yet commercial due many technical challenges. This work explores potential combining two under one umbrella overcome some challenges attractive. It focuses on recuperative autothermal reactor as possible integration options. A tube-in-tube design is proposed in which OCM inner tube MDA outside. numerical study carried out using pseudohomogenous ideal fixed bed models with literature kinetics. systematic tabulated approach used simplify, visualize, structure process view Practical constraints such sizing, pressure drop, reaction performance, axial temperature profile investigated. The effect transfer coefficient, diluents, catalyst profiling, flow direction have been investigated alter profile, avoid thermal run away, improve performance. Multiple thermally coupled OCM-MDA candidates identified. first time that has identified quantified. These merely a starting point toward exploring full opportunities between reaching ultimate option mass same reactor.

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ژورنال

عنوان ژورنال: International Journal of Chemical Engineering

سال: 2023

ISSN: ['1687-8078', '1687-806X']

DOI: https://doi.org/10.1155/2023/8465647